One-Pot Synthesis of Cross-linked Block Copolymer Nanowires via Polymerization-Induced Hierarchical Self-Assembly and Photodimerization

Block copolymer (BCP) nanowires are crucially important in diversified fields. However, their applications typically suffer from a tedious fabrication process, heterogeneous morphology, and degradation. Herein, we propose a facile and robust approach to synthesize stilbene-containing BCP nanowires in homogeneous morphology with high stability at high solid content (5%-20% w/w) in one pot. It is realized by the polymerization-induced hierarchical self-assembly and subsequent photodimerization cross-linking under UV irradiation of stilbene mesogens in the core-forming block in the later stage of polymerization. Because of the strong liquid crystalline ordering and photodimerization of stilbene, the cross-linked nanowires can be obtained over a broad BCP composition, which show robust morphological stability when exposed to solvent dissolution tests and water dispersion stability tests. This efficient approach to stabilized nanowires with homogeneous morphology via in situ cross-linking would be useful in various fields, such as nanomedicine and Pickering emulsifiers.