Mechanically induced multicolor switching based on a single organic molecule

Zhiyong Ma; Mingjun Teng; Zhijian Wang; Shuang Yang; Xinru Jia

doi:10.1002/anie.201306503

Mechanically induced multicolor switching based on a single organic molecule

Zhiyong Ma
, Mingjun Teng
, Zhijian Wang
, Shuang Yang
, Xinru Jia

Peking University

Research output: Contribution to journal › Article › peer-review

210 Scopus citations

Abstract

Asserting its independence: A single organic molecule containing pyrene and rhodamine B chromophores separated by a peptide spacer (see structure) formed a mechanochromic material whose fluorescence could be switched from blue to bluish-green and reddish by grinding. Modulation of the overlapped packing pattern of the pyrene excimer for blue emission was crucial for the reversible tricolored switching observed.

Original language	English
Pages (from-to)	12268-12272
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	47
DOIs	https://doi.org/10.1002/anie.201306503
State	Published - 18 Nov 2013
Externally published	Yes

Keywords

chromophores
excimers
mechanochromic fluorescence
ring opening
tricolored switches

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10.1002/anie.201306503

Cite this

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abstract = "Asserting its independence: A single organic molecule containing pyrene and rhodamine B chromophores separated by a peptide spacer (see structure) formed a mechanochromic material whose fluorescence could be switched from blue to bluish-green and reddish by grinding. Modulation of the overlapped packing pattern of the pyrene excimer for blue emission was crucial for the reversible tricolored switching observed.",

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author = "Zhiyong Ma and Mingjun Teng and Zhijian Wang and Shuang Yang and Xinru Jia",

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AU - Ma, Zhiyong

AU - Teng, Mingjun

AU - Wang, Zhijian

AU - Yang, Shuang

AU - Jia, Xinru

PY - 2013/11/18

Y1 - 2013/11/18

N2 - Asserting its independence: A single organic molecule containing pyrene and rhodamine B chromophores separated by a peptide spacer (see structure) formed a mechanochromic material whose fluorescence could be switched from blue to bluish-green and reddish by grinding. Modulation of the overlapped packing pattern of the pyrene excimer for blue emission was crucial for the reversible tricolored switching observed.

AB - Asserting its independence: A single organic molecule containing pyrene and rhodamine B chromophores separated by a peptide spacer (see structure) formed a mechanochromic material whose fluorescence could be switched from blue to bluish-green and reddish by grinding. Modulation of the overlapped packing pattern of the pyrene excimer for blue emission was crucial for the reversible tricolored switching observed.

KW - chromophores

KW - excimers

KW - mechanochromic fluorescence

KW - ring opening

KW - tricolored switches

UR - https://www.scopus.com/pages/publications/84887507254

U2 - 10.1002/anie.201306503

DO - 10.1002/anie.201306503

M3 - 文章

AN - SCOPUS:84887507254

SN - 1433-7851

VL - 52

SP - 12268

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 47

ER -

Mechanically induced multicolor switching based on a single organic molecule

Abstract

Keywords

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