Mechanical properties and thermal conductivities of 3YSZ-toughened fully stabilized HfO ₂ ceramics

In this work, the 3 mol% yttria stabilized zirconia (3YSZ)composed of tetragonal phase has been introduced into the 10 mol% Er ₂ O ₃ stabilized cubic hafnia (10ErSH)matrix to improve its fracture toughness. The effects of the addition of 3YSZ on the phase composition, microstructure, mechanical properties and thermal conductivities of the 10ErSH have been investigated. The results showed that all the 3YSZ-toughened 10ErSH samples were composed of cubic phase and a little (<10 mol%)monoclinic phase. The introduced tetragonal phase of 3YSZ fully disappeared even when the volume fraction of 3YSZ reached 50%, indicating that the phase transformation occurred during 1500 °C. The fracture toughness for the sample with 50% 3YSZ was improved by 60% compared with the pure 10ErSH ceramics owing to the sub-mico/micro hybrid structure, which changed the crack propagation mode and consumed part of the crack extension energy. Additionally, the thermal conductivity slightly decreased due to the mass and radius misfits induced by substitution atoms (Zr ⁴⁺ , Er ³⁺ and Y ³⁺ ). Considering the improved mechanical and thermal properties, the 3YSZ-toughened 10ErSH ceramics may be alternative TBC materials.