Light-Induced Iodine-Catalyzed Dealkylative Synthesis of Enaminones

Mingming Zhao; Luyao Wang; Yufeng Zhou; Fenke Guo; Tao Yang; Heng Ying Xiong; Teng Wang; Guangwu Zhang

doi:10.1002/adsc.202400631

Light-Induced Iodine-Catalyzed Dealkylative Synthesis of Enaminones

Mingming Zhao
, Luyao Wang
, Yufeng Zhou
, Fenke Guo
, Tao Yang
, Heng Ying Xiong^*
, Teng Wang^*
, Guangwu Zhang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Light mediated iodine-catalyzed synthesis of enaminones through C−N bond cleavage has been described. In addition to substituted ynones, diverse substituted acyclic tertiary amines, and cyclic tertiary amines were also reactive under standard conditions. Selected transformations of the coupling adduct demonstrated the latent utility of this protocol. Preliminary mechanistic studies were also conducted.

Original language	English
Pages (from-to)	4634-4638
Number of pages	5
Journal	Advanced Synthesis and Catalysis
Volume	366
Issue number	22
DOIs	https://doi.org/10.1002/adsc.202400631
State	Published - 19 Nov 2024
Externally published	Yes

Keywords

C−N bond Cleavage
Enaminone
Photocatalysis
Ynones

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10.1002/adsc.202400631

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title = "Light-Induced Iodine-Catalyzed Dealkylative Synthesis of Enaminones",

abstract = "Light mediated iodine-catalyzed synthesis of enaminones through C−N bond cleavage has been described. In addition to substituted ynones, diverse substituted acyclic tertiary amines, and cyclic tertiary amines were also reactive under standard conditions. Selected transformations of the coupling adduct demonstrated the latent utility of this protocol. Preliminary mechanistic studies were also conducted.",

keywords = "C−N bond Cleavage, Enaminone, Photocatalysis, Ynones",

author = "Mingming Zhao and Luyao Wang and Yufeng Zhou and Fenke Guo and Tao Yang and Xiong, \{Heng Ying\} and Teng Wang and Guangwu Zhang",

note = "Publisher Copyright: {\textcopyright} 2024 Wiley-VCH GmbH.",

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doi = "10.1002/adsc.202400631",

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TY - JOUR

T1 - Light-Induced Iodine-Catalyzed Dealkylative Synthesis of Enaminones

AU - Zhao, Mingming

AU - Wang, Luyao

AU - Zhou, Yufeng

AU - Guo, Fenke

AU - Yang, Tao

AU - Xiong, Heng Ying

AU - Wang, Teng

AU - Zhang, Guangwu

PY - 2024/11/19

Y1 - 2024/11/19

N2 - Light mediated iodine-catalyzed synthesis of enaminones through C−N bond cleavage has been described. In addition to substituted ynones, diverse substituted acyclic tertiary amines, and cyclic tertiary amines were also reactive under standard conditions. Selected transformations of the coupling adduct demonstrated the latent utility of this protocol. Preliminary mechanistic studies were also conducted.

AB - Light mediated iodine-catalyzed synthesis of enaminones through C−N bond cleavage has been described. In addition to substituted ynones, diverse substituted acyclic tertiary amines, and cyclic tertiary amines were also reactive under standard conditions. Selected transformations of the coupling adduct demonstrated the latent utility of this protocol. Preliminary mechanistic studies were also conducted.

KW - C−N bond Cleavage

KW - Enaminone

KW - Photocatalysis

KW - Ynones

UR - https://www.scopus.com/pages/publications/85210579417

U2 - 10.1002/adsc.202400631

DO - 10.1002/adsc.202400631

M3 - 文章

AN - SCOPUS:85210579417

SN - 1615-4150

VL - 366

SP - 4634

EP - 4638

JO - Advanced Synthesis and Catalysis

JF - Advanced Synthesis and Catalysis

IS - 22

ER -

Light-Induced Iodine-Catalyzed Dealkylative Synthesis of Enaminones

Abstract

Keywords

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