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Leaching behaviour and environmental risk assessment of heavy metals from electronic solder in acidified soil

  • Xiaodong Lao
  • , Congqian Cheng
  • , Xiaohua Min
  • , Jie Zhao*
  • , Dayu Zhou
  • , Xiaogang Li
  • *Corresponding author for this work
  • Dalian University of Technology
  • Zhoukou Normal University
  • University of Science and Technology Beijing

Research output: Contribution to journalArticlepeer-review

Abstract

The leaching behaviour of Sn and Pb elements from eutectic SnPb solder of electronic waste in acidic soil was investigated through acidification with HCl–H2SO4 solution and compared with saline solution. The amounts of Sn and Pb elements leached, when subjected to acidic soil, are higher than those with saline soil. Evidence for the significantly preferential release of Sn into the leachate is provided; the galvanic couple accelerated such preferential release. Surface product analysis reveals the slight damage of SnPb in saline soil. Serious dissolution due to electrochemical reaction and a thick, porous PbSO4 surface layer are observed in acidified soil, suggesting more severe toxicity potential of Pb in soil rather than in water.

Original languageEnglish
Pages (from-to)17683-17690
Number of pages8
JournalEnvironmental Science and Pollution Research
Volume22
Issue number22
DOIs
StatePublished - 1 Nov 2015
Externally publishedYes

Keywords

  • Acidified soil
  • Electronic solder
  • ICP-MS
  • Leaching

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