Interdendritic Mo homogenization and sub-solidus melting during solution treatment in the Mo-strengthening single crystal superalloys

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Abstract

The interdendritic Mo homogenization and relevant sub-solidus melting are investigated in detail during solution treatment for Mo-strengthening single crystal superalloys. During solidification, NiMo-γ eutectics and Ni2Mo phases precipitate from the residual liquid and the Mo super-saturated interdendritic γ channel, respectively. Due to such super-saturation of Mo, Mo diffuses to interdendritic Mo-rich eutectic in first 5 min of solution treatment, and hence the eutectic sharply propagates, opposite to homogenization of Mo. The excess propagated eutectic causes the occurrence of sub-solidus melting. The proposed Mo-homogenization treatment can completely eliminate such sub-solidus melting.

Original languageEnglish
Pages (from-to)431-435
Number of pages5
JournalJournal of Alloys and Compounds
Volume662
DOIs
StatePublished - 25 Mar 2016

Keywords

  • Diffusion
  • High-temperature alloys
  • Metallography
  • Transmission electron microscopy

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