Influence of temperature on the electrochemical and passivation behavior of 2507 super duplex stainless steel in simulated desulfurized flue gas condensates

Zhongyu Cui; Liwei Wang; Hongtao Ni; Wenkui Hao; Cheng Man; Shuangshuai Chen; Xin Wang; Zhiyong Liu; Xiaogang Li

doi:10.1016/j.corsci.2017.01.016

Influence of temperature on the electrochemical and passivation behavior of 2507 super duplex stainless steel in simulated desulfurized flue gas condensates

Zhongyu Cui
, Liwei Wang^*
, Hongtao Ni
, Wenkui Hao
, Cheng Man
, Shuangshuai Chen
, Xin Wang
, Zhiyong Liu
, Xiaogang Li

^*Corresponding author for this work

Ocean University of China
Qingdao University
Global Energy Interconnection Research Institute Co. Ltd., Beijing
University of Science and Technology Beijing

Research output: Contribution to journal › Article › peer-review

403 Scopus citations

Abstract

Influence of temperature on the electrochemical and passivation behavior of 2507 super duplex stainless steel in the simulated desulfurized flue gas condensates in thermal power plant chimney are investigated. Cathodic reactions are enhanced with temperature, accompanying with the involvement of oxygen reduction when the temperature is raised to 60 °C or higher. The unchanged semiconductor type, enrichment of Cr and thickening of the passive film are observed as the temperature increases. The temperature-induced variations of film structure and doping concentrations are responsible for the degradation of protective ability of the passive film.

Original language	English
Pages (from-to)	31-48
Number of pages	18
Journal	Corrosion Science
Volume	118
DOIs	https://doi.org/10.1016/j.corsci.2017.01.016
State	Published - 1 Apr 2017
Externally published	Yes

Keywords

A: stainless steel
B: EIS
B: XPS
C: acid corrosion
C: passivity

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10.1016/j.corsci.2017.01.016

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@article{14d5a08de26543a7a84f3e8b6dba520f,

title = "Influence of temperature on the electrochemical and passivation behavior of 2507 super duplex stainless steel in simulated desulfurized flue gas condensates",

abstract = "Influence of temperature on the electrochemical and passivation behavior of 2507 super duplex stainless steel in the simulated desulfurized flue gas condensates in thermal power plant chimney are investigated. Cathodic reactions are enhanced with temperature, accompanying with the involvement of oxygen reduction when the temperature is raised to 60 °C or higher. The unchanged semiconductor type, enrichment of Cr and thickening of the passive film are observed as the temperature increases. The temperature-induced variations of film structure and doping concentrations are responsible for the degradation of protective ability of the passive film.",

keywords = "A: stainless steel, B: EIS, B: XPS, C: acid corrosion, C: passivity",

author = "Zhongyu Cui and Liwei Wang and Hongtao Ni and Wenkui Hao and Cheng Man and Shuangshuai Chen and Xin Wang and Zhiyong Liu and Xiaogang Li",

note = "Publisher Copyright: {\textcopyright} 2017 Elsevier Ltd",

year = "2017",

month = apr,

day = "1",

doi = "10.1016/j.corsci.2017.01.016",

language = "英语",

volume = "118",

pages = "31--48",

journal = "Corrosion Science",

issn = "0010-938X",

publisher = "Elsevier Ltd",

}

TY - JOUR

T1 - Influence of temperature on the electrochemical and passivation behavior of 2507 super duplex stainless steel in simulated desulfurized flue gas condensates

AU - Cui, Zhongyu

AU - Wang, Liwei

AU - Ni, Hongtao

AU - Hao, Wenkui

AU - Man, Cheng

AU - Chen, Shuangshuai

AU - Wang, Xin

AU - Liu, Zhiyong

AU - Li, Xiaogang

PY - 2017/4/1

Y1 - 2017/4/1

N2 - Influence of temperature on the electrochemical and passivation behavior of 2507 super duplex stainless steel in the simulated desulfurized flue gas condensates in thermal power plant chimney are investigated. Cathodic reactions are enhanced with temperature, accompanying with the involvement of oxygen reduction when the temperature is raised to 60 °C or higher. The unchanged semiconductor type, enrichment of Cr and thickening of the passive film are observed as the temperature increases. The temperature-induced variations of film structure and doping concentrations are responsible for the degradation of protective ability of the passive film.

AB - Influence of temperature on the electrochemical and passivation behavior of 2507 super duplex stainless steel in the simulated desulfurized flue gas condensates in thermal power plant chimney are investigated. Cathodic reactions are enhanced with temperature, accompanying with the involvement of oxygen reduction when the temperature is raised to 60 °C or higher. The unchanged semiconductor type, enrichment of Cr and thickening of the passive film are observed as the temperature increases. The temperature-induced variations of film structure and doping concentrations are responsible for the degradation of protective ability of the passive film.

KW - A: stainless steel

KW - B: EIS

KW - B: XPS

KW - C: acid corrosion

KW - C: passivity

UR - https://www.scopus.com/pages/publications/85011579965

U2 - 10.1016/j.corsci.2017.01.016

DO - 10.1016/j.corsci.2017.01.016

M3 - 文章

AN - SCOPUS:85011579965

SN - 0010-938X

VL - 118

SP - 31

EP - 48

JO - Corrosion Science

JF - Corrosion Science

ER -

Influence of temperature on the electrochemical and passivation behavior of 2507 super duplex stainless steel in simulated desulfurized flue gas condensates

Abstract

Keywords

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