Highly selective fluorescent calix[4]arene chemosensor for acidic amino acids in pure aqueous media

Shao Yong Li; Yao Wei Xu; She Quan Zeng; Li Min Xiao; Hong Quan Duan; Xue Lian Lin; Jun Min Liu; Cheng Yong Su

doi:10.1016/j.tetlet.2012.04.003

Highly selective fluorescent calix[4]arene chemosensor for acidic amino acids in pure aqueous media

Shao Yong Li
, Yao Wei Xu
, She Quan Zeng
, Li Min Xiao
, Hong Quan Duan
, Xue Lian Lin
, Jun Min Liu^*
, Cheng Yong Su

^*Corresponding author for this work

School of Computer Science and Engineering

Tianjin Medical University
Sun Yat-Sen University

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

A fluorescent chemosensor based on a calix[4]arene derivative conjugated with four thiophene-cyanoarylic acid groups at the upper rim displays high selectivity toward acidic amino acids in pure aqueous media through multiple H-bond interactions. The interactions of Asp/Glu with the chemosensor have been investigated by fluorescence and UV-Vis titrations, ESI-MS assay, ¹H NMR spectra, and molecular modeling method.

Original language	English
Pages (from-to)	2918-2921
Number of pages	4
Journal	Tetrahedron Letters
Volume	53
Issue number	23
DOIs	https://doi.org/10.1016/j.tetlet.2012.04.003
State	Published - 6 Jun 2012

Keywords

Acidic amino acid
Calix[4]arene
Fluorescent chemosensor
Pure aqueous media

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10.1016/j.tetlet.2012.04.003

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title = "Highly selective fluorescent calix[4]arene chemosensor for acidic amino acids in pure aqueous media",

abstract = "A fluorescent chemosensor based on a calix[4]arene derivative conjugated with four thiophene-cyanoarylic acid groups at the upper rim displays high selectivity toward acidic amino acids in pure aqueous media through multiple H-bond interactions. The interactions of Asp/Glu with the chemosensor have been investigated by fluorescence and UV-Vis titrations, ESI-MS assay, 1H NMR spectra, and molecular modeling method.",

keywords = "Acidic amino acid, Calix[4]arene, Fluorescent chemosensor, Pure aqueous media",

author = "Li, \{Shao Yong\} and Xu, \{Yao Wei\} and Zeng, \{She Quan\} and Xiao, \{Li Min\} and Duan, \{Hong Quan\} and Lin, \{Xue Lian\} and Liu, \{Jun Min\} and Su, \{Cheng Yong\}",

year = "2012",

month = jun,

day = "6",

doi = "10.1016/j.tetlet.2012.04.003",

language = "英语",

volume = "53",

pages = "2918--2921",

journal = "Tetrahedron Letters",

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TY - JOUR

T1 - Highly selective fluorescent calix[4]arene chemosensor for acidic amino acids in pure aqueous media

AU - Li, Shao Yong

AU - Xu, Yao Wei

AU - Zeng, She Quan

AU - Xiao, Li Min

AU - Duan, Hong Quan

AU - Lin, Xue Lian

AU - Liu, Jun Min

AU - Su, Cheng Yong

PY - 2012/6/6

Y1 - 2012/6/6

N2 - A fluorescent chemosensor based on a calix[4]arene derivative conjugated with four thiophene-cyanoarylic acid groups at the upper rim displays high selectivity toward acidic amino acids in pure aqueous media through multiple H-bond interactions. The interactions of Asp/Glu with the chemosensor have been investigated by fluorescence and UV-Vis titrations, ESI-MS assay, 1H NMR spectra, and molecular modeling method.

AB - A fluorescent chemosensor based on a calix[4]arene derivative conjugated with four thiophene-cyanoarylic acid groups at the upper rim displays high selectivity toward acidic amino acids in pure aqueous media through multiple H-bond interactions. The interactions of Asp/Glu with the chemosensor have been investigated by fluorescence and UV-Vis titrations, ESI-MS assay, 1H NMR spectra, and molecular modeling method.

KW - Acidic amino acid

KW - Calix[4]arene

KW - Fluorescent chemosensor

KW - Pure aqueous media

UR - https://www.scopus.com/pages/publications/84860835075

U2 - 10.1016/j.tetlet.2012.04.003

DO - 10.1016/j.tetlet.2012.04.003

M3 - 文章

AN - SCOPUS:84860835075

SN - 0040-4039

VL - 53

SP - 2918

EP - 2921

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 23

ER -

Highly selective fluorescent calix[4]arene chemosensor for acidic amino acids in pure aqueous media

Abstract

Keywords

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