Abstract
Nano-structured energetic materials have been recently proposed as novel energy storage media where the exothermic reaction is the key to control the heat release process. The properties of nano-alloys, which can be engineered not only by the particle size, but also by varying their elemental compositions, are very appealing. This work conducted a comparative experimental study of the exothermic characteristics of two nanomaterials in the air, aluminum nanoparticles (nano-Al) and aluminum-copper nanoalloys (nano-AlCu) based on TGA/DSC studies. The results showed that the general exothermic characteristics of nano-AlCu were very similar to that of nano-Al but the nanoalloy was more reactive. The nano-AlCu was oxidized and ignited at lower temperature, and influenced by the heating rate. An early ignition was found for both nanomaterials, and the eutectic melting of the nano-alloy was believed to be mainly responsible for its early ignition.
| Original language | English |
|---|---|
| Pages (from-to) | 19-24 |
| Number of pages | 6 |
| Journal | Powder Technology |
| Volume | 282 |
| DOIs | |
| State | Published - 3 Dec 2015 |
| Externally published | Yes |
Keywords
- Aluminum
- Copper
- Ignition
- Nanoalloy
- Nanofuel
- Oxidation
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