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Energy Transfer between Spatially Separated Entangled Molecules

  • Xiaolan Zhong
  • , Thibault Chervy
  • , Lei Zhang
  • , Anoop Thomas
  • , Jino George
  • , Cyriaque Genet
  • , James A. Hutchison
  • , Thomas W. Ebbesen*
  • *Corresponding author for this work
  • Université de Strasbourg

Research output: Contribution to journalArticlepeer-review

Abstract

Light–matter strong coupling allows for the possibility of entangling the wave functions of different molecules through the light field. We hereby present direct evidence of non-radiative energy transfer well beyond the Förster limit for spatially separated donor and acceptor cyanine dyes strongly coupled to a cavity. The transient dynamics and the static spectra show an energy transfer efficiency approaching 37 % for donor–acceptor distances ≥100 nm. In such systems, the energy transfer process becomes independent of distance as long as the coupling strength is maintained. This is consistent with the entangled and delocalized nature of the polaritonic states.

Original languageEnglish
Pages (from-to)9034-9038
Number of pages5
JournalAngewandte Chemie - International Edition
Volume56
Issue number31
DOIs
StatePublished - 24 Jul 2017
Externally publishedYes

Keywords

  • cyanine dyes
  • non-radiative energy transfer
  • quantum entanglement
  • strong coupling

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