Abstract
The chemical compositions, phases and structures of two oxide films on Alloy 690TT following exposure for 4400 h in pure water with and without lead at 320 °C were studied by surface analysis techniques. The analysis of a lead-doped oxide film prepared by a focused ion beam (FIB) demonstrated that both Cr-rich and Ni-rich oxides were alternatively distributed within the outer layer, whereas the inner layer was porous and poorly protected, causing severe corrosion of the alloy and a thicker film was formed. A duplex film model was proposed for the effects discussion of lead on the oxidation mechanism.
| Original language | English |
|---|---|
| Pages (from-to) | 514-526 |
| Number of pages | 13 |
| Journal | Applied Surface Science |
| Volume | 426 |
| DOIs | |
| State | Published - 31 Dec 2017 |
| Externally published | Yes |
Keywords
- A. Alloy 690TT
- B. Surface analysis
- B. TEM
- C. Duplex film model
- C. High temperature corrosion
- C. Oxidation
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