Dynamic behaviors of inorganic all-solid-state electrochromic device: Role of potential

Qirong Liu; Qianqian Chen; Qianqian Zhang; Guobo Dong; Xiaolan Zhong; Yu Xiao; Marie Paule Delplancke-Ogletree; François Reniers; Xungang Diao

doi:10.1016/j.electacta.2018.02.050

Dynamic behaviors of inorganic all-solid-state electrochromic device: Role of potential

Qirong Liu
, Qianqian Chen
, Qianqian Zhang
, Guobo Dong
, Xiaolan Zhong
, Yu Xiao
, Marie Paule Delplancke-Ogletree
, François Reniers
, Xungang Diao^*

^*Corresponding author for this work

Beihang University
ULB-BUAA Plasma Laboratory for Materials and Environment
Université libre de Bruxelles

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

Applied potential plays a significant role in the properties of electrochromic devices (ECDs), for example, cyclic property, optical modulation, and response rate. In this study, inorganic all-solid-state ECDs with the multilayer structure of Glass/ITO/NiO_x/Ta₂O₅/LiNbO₃/Ta₂O₅/WO₃/ITO were prepared by magnetron sputtering. The potential dependence of charges dynamic behaviors in the ECDs were analyzed on the basis of cyclic voltammograms (CVs), chronoamperograms (CAs), multi-potential steps, and in-situ optical transmittance at 550 nm. Results demonstrated that the trapping of Li⁺ ions in NiO_x layer and in WO₃ layer were responsible for the degradation of electrochromic properties of the ECDs operated at different potential ranges. Besides, the dynamic behavior of Li⁺ ions in WO₃ layer, acting as the primary electrochromic layer in the ECDs, had a crucial influence on the response characteristics of the ECDs. Excellent optical memory effects at randomly electrochromic extent were observed and the corresponding open-circuit potential was relevant to the chemical potential of the ECDs.

Original language	English
Pages (from-to)	617-623
Number of pages	7
Journal	Electrochimica Acta
Volume	269
DOIs	https://doi.org/10.1016/j.electacta.2018.02.050
State	Published - 10 Apr 2018

Keywords

All-solid-state
Applied potential
Dynamic behaviors
Electrochromic device
Inorganic

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10.1016/j.electacta.2018.02.050

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@article{eb4f93b24ce94177b45f6b01e6699071,

title = "Dynamic behaviors of inorganic all-solid-state electrochromic device: Role of potential",

abstract = "Applied potential plays a significant role in the properties of electrochromic devices (ECDs), for example, cyclic property, optical modulation, and response rate. In this study, inorganic all-solid-state ECDs with the multilayer structure of Glass/ITO/NiOx/Ta2O5/LiNbO3/Ta2O5/WO3/ITO were prepared by magnetron sputtering. The potential dependence of charges dynamic behaviors in the ECDs were analyzed on the basis of cyclic voltammograms (CVs), chronoamperograms (CAs), multi-potential steps, and in-situ optical transmittance at 550 nm. Results demonstrated that the trapping of Li+ ions in NiOx layer and in WO3 layer were responsible for the degradation of electrochromic properties of the ECDs operated at different potential ranges. Besides, the dynamic behavior of Li+ ions in WO3 layer, acting as the primary electrochromic layer in the ECDs, had a crucial influence on the response characteristics of the ECDs. Excellent optical memory effects at randomly electrochromic extent were observed and the corresponding open-circuit potential was relevant to the chemical potential of the ECDs.",

keywords = "All-solid-state, Applied potential, Dynamic behaviors, Electrochromic device, Inorganic",

author = "Qirong Liu and Qianqian Chen and Qianqian Zhang and Guobo Dong and Xiaolan Zhong and Yu Xiao and Delplancke-Ogletree, \{Marie Paule\} and Fran{\c c}ois Reniers and Xungang Diao",

note = "Publisher Copyright: {\textcopyright} 2018 Elsevier Ltd",

year = "2018",

month = apr,

day = "10",

doi = "10.1016/j.electacta.2018.02.050",

language = "英语",

volume = "269",

pages = "617--623",

journal = "Electrochimica Acta",

issn = "0013-4686",

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TY - JOUR

T1 - Dynamic behaviors of inorganic all-solid-state electrochromic device

T2 - Role of potential

AU - Liu, Qirong

AU - Chen, Qianqian

AU - Zhang, Qianqian

AU - Dong, Guobo

AU - Zhong, Xiaolan

AU - Xiao, Yu

AU - Delplancke-Ogletree, Marie Paule

AU - Reniers, François

AU - Diao, Xungang

PY - 2018/4/10

Y1 - 2018/4/10

N2 - Applied potential plays a significant role in the properties of electrochromic devices (ECDs), for example, cyclic property, optical modulation, and response rate. In this study, inorganic all-solid-state ECDs with the multilayer structure of Glass/ITO/NiOx/Ta2O5/LiNbO3/Ta2O5/WO3/ITO were prepared by magnetron sputtering. The potential dependence of charges dynamic behaviors in the ECDs were analyzed on the basis of cyclic voltammograms (CVs), chronoamperograms (CAs), multi-potential steps, and in-situ optical transmittance at 550 nm. Results demonstrated that the trapping of Li+ ions in NiOx layer and in WO3 layer were responsible for the degradation of electrochromic properties of the ECDs operated at different potential ranges. Besides, the dynamic behavior of Li+ ions in WO3 layer, acting as the primary electrochromic layer in the ECDs, had a crucial influence on the response characteristics of the ECDs. Excellent optical memory effects at randomly electrochromic extent were observed and the corresponding open-circuit potential was relevant to the chemical potential of the ECDs.

AB - Applied potential plays a significant role in the properties of electrochromic devices (ECDs), for example, cyclic property, optical modulation, and response rate. In this study, inorganic all-solid-state ECDs with the multilayer structure of Glass/ITO/NiOx/Ta2O5/LiNbO3/Ta2O5/WO3/ITO were prepared by magnetron sputtering. The potential dependence of charges dynamic behaviors in the ECDs were analyzed on the basis of cyclic voltammograms (CVs), chronoamperograms (CAs), multi-potential steps, and in-situ optical transmittance at 550 nm. Results demonstrated that the trapping of Li+ ions in NiOx layer and in WO3 layer were responsible for the degradation of electrochromic properties of the ECDs operated at different potential ranges. Besides, the dynamic behavior of Li+ ions in WO3 layer, acting as the primary electrochromic layer in the ECDs, had a crucial influence on the response characteristics of the ECDs. Excellent optical memory effects at randomly electrochromic extent were observed and the corresponding open-circuit potential was relevant to the chemical potential of the ECDs.

KW - All-solid-state

KW - Applied potential

KW - Dynamic behaviors

KW - Electrochromic device

KW - Inorganic

UR - https://www.scopus.com/pages/publications/85044731216

U2 - 10.1016/j.electacta.2018.02.050

DO - 10.1016/j.electacta.2018.02.050

M3 - 文章

AN - SCOPUS:85044731216

SN - 0013-4686

VL - 269

SP - 617

EP - 623

JO - Electrochimica Acta

JF - Electrochimica Acta

ER -

Dynamic behaviors of inorganic all-solid-state electrochromic device: Role of potential

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Keywords

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