Correlation of glass-forming ability to thermal properties in Ti-based bulk metallic glasses

Enhuai Yin; Shujie Pang; Xidong Hui; Min Zhang; Longchao Zhuo; Chen Chen; Tao Zhang

doi:10.1016/j.jallcom.2012.07.037

Correlation of glass-forming ability to thermal properties in Ti-based bulk metallic glasses

Enhuai Yin
, Shujie Pang
, Xidong Hui
, Min Zhang
, Longchao Zhuo
, Chen Chen
, Tao Zhang^*

^*Corresponding author for this work

School of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Ti_45.8Zr_6.2Cu_45-xNi _xSn₂Si₁ (x = 0, 2, 4, 5, 7, 9, 11, 13 and 15 at.%) and Ti_52-yZr_yCu_40.9Ni _5.1Sn₂ (y = 4, 6, 8, 10, 12, 14 and 16 at.%) bulk metallic glasses with critical diameters up to 4 mm were prepared by copper mold casting. The thermal properties and crystallization behavior of these Ti-based glassy alloys have been investigated in detail. It is shown that the higher the onset temperature of the last crystallization event (T_n), the larger the glass forming ability (GFA). By considering the comprehensive effect of glass transition temperature (T_g), the onset temperature of the first crystallization event (T_x), T_n and liquidus temperature (T_l), we proposed a parameter N = (2T_x - T_g + T_n)/2T_l for the evaluation of GFA. It is found that this criterion is particularly effective for the BMGs which show multistage crystallization events upon heating.

Original language	English
Pages (from-to)	7-13
Number of pages	7
Journal	Journal of Alloys and Compounds
Volume	546
DOIs	https://doi.org/10.1016/j.jallcom.2012.07.037
State	Published - 2013

Keywords

Metallic glasses
Rapid-solidification
Thermal analysis

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10.1016/j.jallcom.2012.07.037

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@article{a51f184bddd64ba797e95d8e9df461c9,

title = "Correlation of glass-forming ability to thermal properties in Ti-based bulk metallic glasses",

abstract = "Ti45.8Zr6.2Cu45-xNi xSn2Si1 (x = 0, 2, 4, 5, 7, 9, 11, 13 and 15 at.\%) and Ti52-yZryCu40.9Ni 5.1Sn2 (y = 4, 6, 8, 10, 12, 14 and 16 at.\%) bulk metallic glasses with critical diameters up to 4 mm were prepared by copper mold casting. The thermal properties and crystallization behavior of these Ti-based glassy alloys have been investigated in detail. It is shown that the higher the onset temperature of the last crystallization event (Tn), the larger the glass forming ability (GFA). By considering the comprehensive effect of glass transition temperature (Tg), the onset temperature of the first crystallization event (Tx), Tn and liquidus temperature (Tl), we proposed a parameter N = (2Tx - Tg + Tn)/2Tl for the evaluation of GFA. It is found that this criterion is particularly effective for the BMGs which show multistage crystallization events upon heating.",

keywords = "Metallic glasses, Rapid-solidification, Thermal analysis",

author = "Enhuai Yin and Shujie Pang and Xidong Hui and Min Zhang and Longchao Zhuo and Chen Chen and Tao Zhang",

year = "2013",

doi = "10.1016/j.jallcom.2012.07.037",

language = "英语",

volume = "546",

pages = "7--13",

journal = "Journal of Alloys and Compounds",

issn = "0925-8388",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Correlation of glass-forming ability to thermal properties in Ti-based bulk metallic glasses

AU - Yin, Enhuai

AU - Pang, Shujie

AU - Hui, Xidong

AU - Zhang, Min

AU - Zhuo, Longchao

AU - Chen, Chen

AU - Zhang, Tao

PY - 2013

Y1 - 2013

N2 - Ti45.8Zr6.2Cu45-xNi xSn2Si1 (x = 0, 2, 4, 5, 7, 9, 11, 13 and 15 at.%) and Ti52-yZryCu40.9Ni 5.1Sn2 (y = 4, 6, 8, 10, 12, 14 and 16 at.%) bulk metallic glasses with critical diameters up to 4 mm were prepared by copper mold casting. The thermal properties and crystallization behavior of these Ti-based glassy alloys have been investigated in detail. It is shown that the higher the onset temperature of the last crystallization event (Tn), the larger the glass forming ability (GFA). By considering the comprehensive effect of glass transition temperature (Tg), the onset temperature of the first crystallization event (Tx), Tn and liquidus temperature (Tl), we proposed a parameter N = (2Tx - Tg + Tn)/2Tl for the evaluation of GFA. It is found that this criterion is particularly effective for the BMGs which show multistage crystallization events upon heating.

AB - Ti45.8Zr6.2Cu45-xNi xSn2Si1 (x = 0, 2, 4, 5, 7, 9, 11, 13 and 15 at.%) and Ti52-yZryCu40.9Ni 5.1Sn2 (y = 4, 6, 8, 10, 12, 14 and 16 at.%) bulk metallic glasses with critical diameters up to 4 mm were prepared by copper mold casting. The thermal properties and crystallization behavior of these Ti-based glassy alloys have been investigated in detail. It is shown that the higher the onset temperature of the last crystallization event (Tn), the larger the glass forming ability (GFA). By considering the comprehensive effect of glass transition temperature (Tg), the onset temperature of the first crystallization event (Tx), Tn and liquidus temperature (Tl), we proposed a parameter N = (2Tx - Tg + Tn)/2Tl for the evaluation of GFA. It is found that this criterion is particularly effective for the BMGs which show multistage crystallization events upon heating.

KW - Metallic glasses

KW - Rapid-solidification

KW - Thermal analysis

UR - https://www.scopus.com/pages/publications/84866517868

U2 - 10.1016/j.jallcom.2012.07.037

DO - 10.1016/j.jallcom.2012.07.037

M3 - 文章

AN - SCOPUS:84866517868

SN - 0925-8388

VL - 546

SP - 7

EP - 13

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

ER -

Correlation of glass-forming ability to thermal properties in Ti-based bulk metallic glasses

Abstract

Keywords

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