Caustic corrosion cracking of the octene tube in the fertilizer industry

  • Menghao Liu
  • , Ziyang Zhang
  • , Peilin Chai
  • , Chuang Guo
  • , Cuiwei Du
  • , Zhiyong Liu*
  • , Meihui Sun
  • , Endian Fan
  • , Xueliang Shang
  • , Xiaogang Li
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

A carbon steel octene tube has leaked from the fusion zone and caused economic losses. The failure process and mechanism were investigated in this work, by means of scanning electron microscope, electron backscattered diffraction, energy-dispersive X-ray spectroscopy and Scanning Kelvin probe force microscopy. Results showed the failure was attributed to caustic corrosion cracking. The cracking mechanism is anodic dissolution mechanism, including film rupture, intergranular corrosion and repassivation processes. A less corrosion-resistant chemical composition, a larger residual stress after welding and a higher content of hydroxyl ions synthetically resulted in the cracking synthetically. Hydroxyl ions firstly reacted with passive film and caused initiation of intergranular cracks. Residual stress and intergranular corrosion result in an intergranular propagation of SCC cracks.

Original languageEnglish
Article number105953
JournalEngineering Failure Analysis
Volume133
DOIs
StatePublished - Mar 2022
Externally publishedYes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

  1. SDG 2 - Zero Hunger
    SDG 2 Zero Hunger

Keywords

  • Carbon steel
  • Caustic corrosion cracking
  • Octene tube

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