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Calculation and analysis of diffusivity of point defects in passive film formed on 2205 duplex stainless steel and 316l austenitic stainless steel

  • Zuojia Liu*
  • , Xuequn Cheng
  • , Xiaohui Liu
  • , Xiaogang Li
  • *Corresponding author for this work
  • University of Science and Technology Beijing
  • SINOPEC

Research output: Contribution to journalArticlepeer-review

Abstract

The diffusivity of point defects in the passive film formed on 2205 duplex stainless steel and 316L stainless steel in NaCl solution was calculated by means of capacitance measurement and PDM (point defect model). The calculated result was testified and analyzed by experimental steady current density of passive film and PDM. It is showed that the order of magnitude of diffusivity is about 10-23 cm2/s~10-20 cm2/s, and the diffusivity of 2205 DSS is less than 316L SS in simulated ocean solution. It is concluded that the diffusion of point defect which is caused by oxygen vacancy in 2205 DSS is harder than 316L SS, so in contrast to 316L SS, the passive film of 2205 DSS is much densified and compact with completeness and excellent protection.

Original languageEnglish
Pages (from-to)273-277
Number of pages5
JournalJournal of the Chinese Society of Corrosion and Protection
Volume30
Issue number4
StatePublished - 2010
Externally publishedYes

Keywords

  • Capacitance measurement
  • Diffusivity
  • Passive film
  • Point defect model
  • Steady current density

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