Air-stable n-type semiconductor: Core-perfluoroalkylated perylene bisimides

Yan Li; Lin Tan; Zhaohui Wang; Hualei Qian; Yubai Shi; Wenping Hu

doi:10.1021/ol703046w

Air-stable n-type semiconductor: Core-perfluoroalkylated perylene bisimides

Yan Li
, Lin Tan
, Zhaohui Wang^*
, Hualei Qian
, Yubai Shi
, Wenping Hu

^*Corresponding author for this work

CAS - Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

129 Scopus citations

Abstract

A series of core-perfluoroalkylated perylene bisimides (PBIs) have been efficiently synthesized by copper-mediated perfluoroalkylation of dibrominated PBIs. Their aromatic cores are highly twisted due to the steric encumbrance in the bay regions as revealed by single-crystal X-ray analysis. The organic field-effect transistors (OFETs) incorporating these new n-type semiconductors show remarkable air-stability and good field effect mobility.

Original language	English
Pages (from-to)	529-532
Number of pages	4
Journal	Organic Letters
Volume	10
Issue number	4
DOIs	https://doi.org/10.1021/ol703046w
State	Published - 21 Feb 2008
Externally published	Yes

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10.1021/ol703046w

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title = "Air-stable n-type semiconductor: Core-perfluoroalkylated perylene bisimides",

abstract = "A series of core-perfluoroalkylated perylene bisimides (PBIs) have been efficiently synthesized by copper-mediated perfluoroalkylation of dibrominated PBIs. Their aromatic cores are highly twisted due to the steric encumbrance in the bay regions as revealed by single-crystal X-ray analysis. The organic field-effect transistors (OFETs) incorporating these new n-type semiconductors show remarkable air-stability and good field effect mobility.",

author = "Yan Li and Lin Tan and Zhaohui Wang and Hualei Qian and Yubai Shi and Wenping Hu",

year = "2008",

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journal = "Organic Letters",

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T1 - Air-stable n-type semiconductor

T2 - Core-perfluoroalkylated perylene bisimides

AU - Li, Yan

AU - Tan, Lin

AU - Wang, Zhaohui

AU - Qian, Hualei

AU - Shi, Yubai

AU - Hu, Wenping

PY - 2008/2/21

Y1 - 2008/2/21

N2 - A series of core-perfluoroalkylated perylene bisimides (PBIs) have been efficiently synthesized by copper-mediated perfluoroalkylation of dibrominated PBIs. Their aromatic cores are highly twisted due to the steric encumbrance in the bay regions as revealed by single-crystal X-ray analysis. The organic field-effect transistors (OFETs) incorporating these new n-type semiconductors show remarkable air-stability and good field effect mobility.

AB - A series of core-perfluoroalkylated perylene bisimides (PBIs) have been efficiently synthesized by copper-mediated perfluoroalkylation of dibrominated PBIs. Their aromatic cores are highly twisted due to the steric encumbrance in the bay regions as revealed by single-crystal X-ray analysis. The organic field-effect transistors (OFETs) incorporating these new n-type semiconductors show remarkable air-stability and good field effect mobility.

UR - https://www.scopus.com/pages/publications/39749098589

U2 - 10.1021/ol703046w

DO - 10.1021/ol703046w

M3 - 文章

AN - SCOPUS:39749098589

SN - 1523-7060

VL - 10

SP - 529

EP - 532

JO - Organic Letters

JF - Organic Letters

IS - 4

ER -

Air-stable n-type semiconductor: Core-perfluoroalkylated perylene bisimides

Abstract

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