A versatile preparation of highly active ZIF-based non-PGM catalysts through solid state synthesis

D. Zhao; J. L. Shui; L. R. Grabstanowicz; D. J. Liu

doi:10.1149/06403.0253ecst

A versatile preparation of highly active ZIF-based non-PGM catalysts through solid state synthesis

D. Zhao
, J. L. Shui
, L. R. Grabstanowicz
, D. J. Liu^*

^*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

1 Scopus citations

Abstract

Current proton exchange membrane fuel cell uses precious metal such as platinum as the catalyst to promote electrochemical reactions at both electrodes, which presents a significant cost barrier for large scale fuel cell commercialization. To replace precious metal with other low cost, earth-abundant materials represents a critical yet incredible challenging area in future fuel cell research. To compete with the precious metal based catalyst, the non-platinum group metal (non-PGM) materials must have higher active site density and improved turn-over-frequency. In this report, we discuss a new method of preparing "support-free", low-cost non-PGM catalysts produced by using "one-pot" synthesized metal-organic frameworks. The new approach led to the formation of catalysts with high-density of active site and high efficiency towards the oxygen reduction reaction in the acidic medium, measured by rotating disk electrode in oxygen saturated electrolyte and under single fuel cell operating condition.

Original language	English
Title of host publication	Polymer Electrolyte Fuel Cells 14
Editors	K. Shinohara, S. R. Narayanan, K. Swider-Lyons, A. Weber, C. Coutanceau, R. Mantz, H. A. Gasteiger, D. Jones, M. Edmundson, S. Mitsushima, V. Ramani, Y. Meas, T. Fuller, H. Uchida, F. N. Buchi, K. A. Perry, T. J. Schmidt, J. M. Fenton, P. Strasser
Publisher	Electrochemical Society Inc.
Pages	253-260
Number of pages	8
Edition	3
ISBN (Electronic)	9781607685395
DOIs	https://doi.org/10.1149/06403.0253ecst
State	Published - 2014
Externally published	Yes
Event	14th Polymer Electrolyte Fuel Cell Symposium, PEFC 2014 - 226th ECS Meeting - Cancun, Mexico Duration: 5 Oct 2014 → 9 Oct 2014

Publication series

Name	ECS Transactions
Number	3
Volume	64
ISSN (Print)	1938-5862
ISSN (Electronic)	1938-6737

Conference

Conference	14th Polymer Electrolyte Fuel Cell Symposium, PEFC 2014 - 226th ECS Meeting
Country/Territory	Mexico
City	Cancun
Period	5/10/14 → 9/10/14

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10.1149/06403.0253ecst

Cite this

Zhao, D., Shui, J. L., Grabstanowicz, L. R., & Liu, D. J. (2014). A versatile preparation of highly active ZIF-based non-PGM catalysts through solid state synthesis. In K. Shinohara, S. R. Narayanan, K. Swider-Lyons, A. Weber, C. Coutanceau, R. Mantz, H. A. Gasteiger, D. Jones, M. Edmundson, S. Mitsushima, V. Ramani, Y. Meas, T. Fuller, H. Uchida, F. N. Buchi, K. A. Perry, T. J. Schmidt, J. M. Fenton, & P. Strasser (Eds.), Polymer Electrolyte Fuel Cells 14 (3 ed., pp. 253-260). (ECS Transactions; Vol. 64, No. 3). Electrochemical Society Inc.. https://doi.org/10.1149/06403.0253ecst

Zhao, D. ; Shui, J. L. ; Grabstanowicz, L. R. et al. / A versatile preparation of highly active ZIF-based non-PGM catalysts through solid state synthesis. Polymer Electrolyte Fuel Cells 14. editor / K. Shinohara ; S. R. Narayanan ; K. Swider-Lyons ; A. Weber ; C. Coutanceau ; R. Mantz ; H. A. Gasteiger ; D. Jones ; M. Edmundson ; S. Mitsushima ; V. Ramani ; Y. Meas ; T. Fuller ; H. Uchida ; F. N. Buchi ; K. A. Perry ; T. J. Schmidt ; J. M. Fenton ; P. Strasser. 3. ed. Electrochemical Society Inc., 2014. pp. 253-260 (ECS Transactions; 3).

@inproceedings{6dbc9e7fa449497b81595ace0ec66d4e,

title = "A versatile preparation of highly active ZIF-based non-PGM catalysts through solid state synthesis",

abstract = "Current proton exchange membrane fuel cell uses precious metal such as platinum as the catalyst to promote electrochemical reactions at both electrodes, which presents a significant cost barrier for large scale fuel cell commercialization. To replace precious metal with other low cost, earth-abundant materials represents a critical yet incredible challenging area in future fuel cell research. To compete with the precious metal based catalyst, the non-platinum group metal (non-PGM) materials must have higher active site density and improved turn-over-frequency. In this report, we discuss a new method of preparing {"}support-free{"}, low-cost non-PGM catalysts produced by using {"}one-pot{"} synthesized metal-organic frameworks. The new approach led to the formation of catalysts with high-density of active site and high efficiency towards the oxygen reduction reaction in the acidic medium, measured by rotating disk electrode in oxygen saturated electrolyte and under single fuel cell operating condition.",

author = "D. Zhao and Shui, \{J. L.\} and Grabstanowicz, \{L. R.\} and Liu, \{D. J.\}",

note = "Publisher Copyright: {\textcopyright} The Electrochemical Society.; 14th Polymer Electrolyte Fuel Cell Symposium, PEFC 2014 - 226th ECS Meeting ; Conference date: 05-10-2014 Through 09-10-2014",

year = "2014",

doi = "10.1149/06403.0253ecst",

language = "英语",

series = "ECS Transactions",

publisher = "Electrochemical Society Inc.",

number = "3",

pages = "253--260",

editor = "K. Shinohara and Narayanan, \{S. R.\} and K. Swider-Lyons and A. Weber and C. Coutanceau and R. Mantz and Gasteiger, \{H. A.\} and D. Jones and M. Edmundson and S. Mitsushima and V. Ramani and Y. Meas and T. Fuller and H. Uchida and Buchi, \{F. N.\} and Perry, \{K. A.\} and Schmidt, \{T. J.\} and Fenton, \{J. M.\} and P. Strasser",

booktitle = "Polymer Electrolyte Fuel Cells 14",

address = "美国",

edition = "3",

}

Zhao, D, Shui, JL, Grabstanowicz, LR & Liu, DJ 2014, A versatile preparation of highly active ZIF-based non-PGM catalysts through solid state synthesis. in K Shinohara, SR Narayanan, K Swider-Lyons, A Weber, C Coutanceau, R Mantz, HA Gasteiger, D Jones, M Edmundson, S Mitsushima, V Ramani, Y Meas, T Fuller, H Uchida, FN Buchi, KA Perry, TJ Schmidt, JM Fenton & P Strasser (eds), Polymer Electrolyte Fuel Cells 14. 3 edn, ECS Transactions, no. 3, vol. 64, Electrochemical Society Inc., pp. 253-260, 14th Polymer Electrolyte Fuel Cell Symposium, PEFC 2014 - 226th ECS Meeting, Cancun, Mexico, 5/10/14. https://doi.org/10.1149/06403.0253ecst

A versatile preparation of highly active ZIF-based non-PGM catalysts through solid state synthesis. / Zhao, D.; Shui, J. L.; Grabstanowicz, L. R. et al.
Polymer Electrolyte Fuel Cells 14. ed. / K. Shinohara; S. R. Narayanan; K. Swider-Lyons; A. Weber; C. Coutanceau; R. Mantz; H. A. Gasteiger; D. Jones; M. Edmundson; S. Mitsushima; V. Ramani; Y. Meas; T. Fuller; H. Uchida; F. N. Buchi; K. A. Perry; T. J. Schmidt; J. M. Fenton; P. Strasser. 3. ed. Electrochemical Society Inc., 2014. p. 253-260 (ECS Transactions; Vol. 64, No. 3).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - A versatile preparation of highly active ZIF-based non-PGM catalysts through solid state synthesis

AU - Zhao, D.

AU - Shui, J. L.

AU - Grabstanowicz, L. R.

AU - Liu, D. J.

N1 - Publisher Copyright: © The Electrochemical Society.

PY - 2014

Y1 - 2014

N2 - Current proton exchange membrane fuel cell uses precious metal such as platinum as the catalyst to promote electrochemical reactions at both electrodes, which presents a significant cost barrier for large scale fuel cell commercialization. To replace precious metal with other low cost, earth-abundant materials represents a critical yet incredible challenging area in future fuel cell research. To compete with the precious metal based catalyst, the non-platinum group metal (non-PGM) materials must have higher active site density and improved turn-over-frequency. In this report, we discuss a new method of preparing "support-free", low-cost non-PGM catalysts produced by using "one-pot" synthesized metal-organic frameworks. The new approach led to the formation of catalysts with high-density of active site and high efficiency towards the oxygen reduction reaction in the acidic medium, measured by rotating disk electrode in oxygen saturated electrolyte and under single fuel cell operating condition.

AB - Current proton exchange membrane fuel cell uses precious metal such as platinum as the catalyst to promote electrochemical reactions at both electrodes, which presents a significant cost barrier for large scale fuel cell commercialization. To replace precious metal with other low cost, earth-abundant materials represents a critical yet incredible challenging area in future fuel cell research. To compete with the precious metal based catalyst, the non-platinum group metal (non-PGM) materials must have higher active site density and improved turn-over-frequency. In this report, we discuss a new method of preparing "support-free", low-cost non-PGM catalysts produced by using "one-pot" synthesized metal-organic frameworks. The new approach led to the formation of catalysts with high-density of active site and high efficiency towards the oxygen reduction reaction in the acidic medium, measured by rotating disk electrode in oxygen saturated electrolyte and under single fuel cell operating condition.

UR - https://www.scopus.com/pages/publications/84921280747

U2 - 10.1149/06403.0253ecst

DO - 10.1149/06403.0253ecst

M3 - 会议稿件

AN - SCOPUS:84921280747

T3 - ECS Transactions

SP - 253

EP - 260

BT - Polymer Electrolyte Fuel Cells 14

A2 - Shinohara, K.

A2 - Narayanan, S. R.

A2 - Swider-Lyons, K.

A2 - Weber, A.

A2 - Coutanceau, C.

A2 - Mantz, R.

A2 - Gasteiger, H. A.

A2 - Jones, D.

A2 - Edmundson, M.

A2 - Mitsushima, S.

A2 - Ramani, V.

A2 - Meas, Y.

A2 - Fuller, T.

A2 - Uchida, H.

A2 - Buchi, F. N.

A2 - Perry, K. A.

A2 - Schmidt, T. J.

A2 - Fenton, J. M.

A2 - Strasser, P.

PB - Electrochemical Society Inc.

T2 - 14th Polymer Electrolyte Fuel Cell Symposium, PEFC 2014 - 226th ECS Meeting

Y2 - 5 October 2014 through 9 October 2014

ER -

Zhao D, Shui JL, Grabstanowicz LR, Liu DJ. A versatile preparation of highly active ZIF-based non-PGM catalysts through solid state synthesis. In Shinohara K, Narayanan SR, Swider-Lyons K, Weber A, Coutanceau C, Mantz R, Gasteiger HA, Jones D, Edmundson M, Mitsushima S, Ramani V, Meas Y, Fuller T, Uchida H, Buchi FN, Perry KA, Schmidt TJ, Fenton JM, Strasser P, editors, Polymer Electrolyte Fuel Cells 14. 3 ed. Electrochemical Society Inc. 2014. p. 253-260. (ECS Transactions; 3). doi: 10.1149/06403.0253ecst

A versatile preparation of highly active ZIF-based non-PGM catalysts through solid state synthesis

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