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A novel photo-switched electrochemical behaviour of a charge-transfer complex containing hemicyanine cation and nickel complex anion in a Langmuir-Blodgett film

  • Jin Zhai
  • , Liang Bing Gan
  • , Chun Hui Huang*
  • *Corresponding author for this work
  • Peking University

Research output: Contribution to journalArticlepeer-review

Abstract

A novel photo-switched electrochemical behaviour of a new compound, bis{(E)-N-octadecyl-4-[2-(4-diethylamino-phenyl)ethenyl] pyridinium}[bis(2-thione-1,3-dithiol-4,5-dimer-capto)nickel] ([Et 2 N-C 6 H 4 -CHx=CH-C 5 H 4 N-C 18 H 37 ] 2 Ni(dmit) 2 , compound A) was first observed on monolayer modified ITO electrode. Its possible mechanism is proposed.

Original languageEnglish
Pages (from-to)223-226
Number of pages4
JournalApplied Surface Science
Volume140
Issue number1-2
DOIs
StatePublished - Feb 1999
Externally publishedYes

Keywords

  • Charge-transfer complex
  • Electrochemistry
  • LB films

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