A novel approach to ortho-carborane by decarboranylation of 1-(isopropyl benzoate)-1,2-dicarba-closo-dodecaborane

Chen Feng; Haicheng Zhang; Jiping Yang; Gong Chen

doi:10.1016/j.tetlet.2015.03.003

A novel approach to ortho-carborane by decarboranylation of 1-(isopropyl benzoate)-1,2-dicarba-closo-dodecaborane

Chen Feng
, Haicheng Zhang
, Jiping Yang
, Gong Chen^*

^*Corresponding author for this work

School of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Abstract A novel approach was successfully developed for the synthesis of ortho-carborane [1,2-dicarba-closo-dodecaborane(12)] by reaction of 1-(isopropyl benzoate)-1,2-dicarba-closo-dodecaborane with KOH in methanol at 20 C. A decarboranylation in base of the first formed alcoholysis intermediate product 1-(2-propanol)-1,2-dicarba-closo-dodecaborane was suggested for this process.

Original language	English
Article number	46006
Pages (from-to)	2027-2029
Number of pages	3
Journal	Tetrahedron Letters
Volume	56
Issue number	15
DOIs	https://doi.org/10.1016/j.tetlet.2015.03.003
State	Published - 8 Apr 2015

Keywords

Alcoholysis
Base
Decarboranylation
ortho-Carborane

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10.1016/j.tetlet.2015.03.003

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title = "A novel approach to ortho-carborane by decarboranylation of 1-(isopropyl benzoate)-1,2-dicarba-closo-dodecaborane",

abstract = "Abstract A novel approach was successfully developed for the synthesis of ortho-carborane [1,2-dicarba-closo-dodecaborane(12)] by reaction of 1-(isopropyl benzoate)-1,2-dicarba-closo-dodecaborane with KOH in methanol at 20 C. A decarboranylation in base of the first formed alcoholysis intermediate product 1-(2-propanol)-1,2-dicarba-closo-dodecaborane was suggested for this process.",

keywords = "Alcoholysis, Base, Decarboranylation, ortho-Carborane",

author = "Chen Feng and Haicheng Zhang and Jiping Yang and Gong Chen",

year = "2015",

month = apr,

day = "8",

doi = "10.1016/j.tetlet.2015.03.003",

language = "英语",

volume = "56",

pages = "2027--2029",

journal = "Tetrahedron Letters",

issn = "0040-4039",

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TY - JOUR

T1 - A novel approach to ortho-carborane by decarboranylation of 1-(isopropyl benzoate)-1,2-dicarba-closo-dodecaborane

AU - Feng, Chen

AU - Zhang, Haicheng

AU - Yang, Jiping

AU - Chen, Gong

PY - 2015/4/8

Y1 - 2015/4/8

N2 - Abstract A novel approach was successfully developed for the synthesis of ortho-carborane [1,2-dicarba-closo-dodecaborane(12)] by reaction of 1-(isopropyl benzoate)-1,2-dicarba-closo-dodecaborane with KOH in methanol at 20 C. A decarboranylation in base of the first formed alcoholysis intermediate product 1-(2-propanol)-1,2-dicarba-closo-dodecaborane was suggested for this process.

AB - Abstract A novel approach was successfully developed for the synthesis of ortho-carborane [1,2-dicarba-closo-dodecaborane(12)] by reaction of 1-(isopropyl benzoate)-1,2-dicarba-closo-dodecaborane with KOH in methanol at 20 C. A decarboranylation in base of the first formed alcoholysis intermediate product 1-(2-propanol)-1,2-dicarba-closo-dodecaborane was suggested for this process.

KW - Alcoholysis

KW - Base

KW - Decarboranylation

KW - ortho-Carborane

UR - https://www.scopus.com/pages/publications/84925382567

U2 - 10.1016/j.tetlet.2015.03.003

DO - 10.1016/j.tetlet.2015.03.003

M3 - 文章

AN - SCOPUS:84925382567

SN - 0040-4039

VL - 56

SP - 2027

EP - 2029

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 15

M1 - 46006

ER -

A novel approach to ortho-carborane by decarboranylation of 1-(isopropyl benzoate)-1,2-dicarba-closo-dodecaborane

Abstract

Keywords

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