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A new modification of NaCoPO4 with the zeolite ABW structure

  • Ann M. Chippindale*
  • , Andrew R. Cowley
  • , Jiesheng Chen
  • , Qiuming Gao
  • , Ruren Xu
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

The title compound, sodium cobalt(II) phosphate, a new polymorph of NaCoPO4, crystallizes as a monoclinic modification of the zeolite ABW structure. The five-coordinate Na+ cations reside within channels running through an open cobalt-phosphate framework constructed from four-, six- and eight-membered rings of alternating CoO4 and PO4 tetrahedra. The channels are enclosed by the eight-membered rings.

Original languageEnglish
Pages (from-to)845-847
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume55
Issue number6
DOIs
StatePublished - 15 Jun 1999
Externally publishedYes

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